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11.
《Advanced Powder Technology》2022,33(12):103847
We investigate synthesis, phase evolution, hollow and porous structure and magnetic properties of quasi-amorphous intermediate phase (QUAIPH) and hematite (α-Fe2O3) nanostructure synthesized by annealing of akaganeite (β-FeOOH) nanorods. It is found that the annealing temperature determines the phase composition of the products, the crystal structure/size dictates the magnetic properties whereas the final nanorod morphology is determined by the starting material. Annealing of β-FeOOH at ~300 °C resulted in the formation of hollow QUAIPH nanorods. The synthesized material shows low-cytotoxicity, superparamagnetism and good transverse relaxivity, which is rarely reported for QUAIPH. The QUAIPH nanorods started to transform to porous hematite nanostructures at ~350 °C and phase transformation was completed at 600 °C. During the annealing, the crystal structure changed from monoclinic (akaganeite) to quasi-amorphous and rhombohedral (hematite). Unusually, the crystallite size first decreased (akaganeite → QUAIPH) and then increased (QUAIPH → hematite) during annealing whereas the nanorods retained particle shape. The magnetic properties of the samples changed from antiferromagnetic (akaganeite) to superparamagnetic with blocking temperature TB = 84 K (QUAIPH) and finally to weak-ferromagnetic with the Morin transition at TM = 244 K and high coercivity HC = 1652 Oe (hematite). The low-cytotoxicity and MRI relaxivity (r2 = 5.80 mM?1 s?1 (akaganeite), r2 = 4.31 mM?1 s?1 (QUAIPH) and r2 = 5.17 mM?1 s?1 (hematite)) reveal potential for biomedical applications. 相似文献
12.
《International Journal of Hydrogen Energy》2022,47(34):15480-15490
The rapid increase in energy consumption has severely rehabilitated human life urging to develop reliable and environmental friendly energy storage devices. Target oriented, systematic approach has been adopted to synthesis La doped CeO2 nanostructures with percentage as LaxCe1-xO2 (X = 0,1,3,5,7) for potential super capacitors applications. Morphological doping impact on H2 production, electrochemical and optical properties are thoroughly investigated. XRD studies revealed the crystalline phase purity and attained approximately 35 nm average crystallite size. The SEM images exposed that primary morphology nano-particles has been tuned into nanorods by increasing the La concentration in CeO2 with size range 40~60 nm. CV graphs depicted that the prepared electrodes obey the pseudo capacitive faradaic reactions behavior in nature. Maximum capacitance (925 F g-1) has been achieved by La0·05Ce0·95O2 which is better than numerous reported materials. The La0·05Ce0·95O2 also exhibited excellent GCD stability with 87.8% retention exhibiting it suitability for supercapacitor applications. Furthermore, the La0·05Ce0·95O2 showed the significantly higher H2 (9 μmol h?1g?1) production rate as compared to undoped CeO2 and La0·01Ce0·99O2, La0·03Ce0·97O2 samples. This higher production is attributed to the recombination rate and have strong substantial correlation with optical characteristics. 相似文献
13.
《International Journal of Hydrogen Energy》2022,47(43):18831-18856
This study represents the results of the analysis and optimization of an integrated system for cogenerating electricity and freshwater. This setup consists of a Solid Oxide Fuel cell (SOFC) for producing electricity. Unburned fuel of the SOFC is burned in the afterburner to increase the temperature of the SOFC's outlet gasses and operate a Gas turbine (GT) to produce additional power and operate the air compressor. At the bottom of this cycle, a combined setup of a Multi-Effect Desalination (MED) and Reverse Osmosis (RO) is considered to produce freshwater from the unused heat capacity of the GT's exhaust gasses. Also, a Stirling engine is used in the fuel supply line to increase the fuel's temperature. Using LNG and the Stirling engine will replace the fuel compressor with a pump which increases the system performance and eliminates the need for the expansion valve. To study the system performance a mathematical model is developed in Engineering Equation Solver (EES) program. Then, the system's simulated data from the EES has been sent to MATLAB to promote the best operating condition based on the optimization criteria. An energetic, exergetic, economic, and environmental analysis has been performed and a Non-dominated Sorting Genetic Algorithm (NSGA-II) is used to achieve the goal. The two-objective optimization is performed to maximize the exergetic efficiency of the proposed system while minimizing the system's total cost of production. This cost is a weighted distribution of the Levelized Cost of Electricity (LCOE) and Levelized Cost of freshwater (LCOW). The results showed that the exergetic and energetic efficiencies of the system can reach 73.5% and 69.06% at the optimum point. The total electricity production of the system is 99 MW. The production cost is 11.71 Cents/kWh, of which 1.04 Cents/kWh is emission-related and environmental taxes. The freshwater production rate is 42.44 kg/s which costs 4.38 USD/m3. 相似文献
14.
15.
《International Journal of Hydrogen Energy》2022,47(54):22738-22751
Transition metal-based electrocatalysts supported on carbon substrates face the challenges of anodic corrosion of carbon during oxygen evolution reaction at high oxidation potential. The role of electrophilic functional groups (carbonyl, pyridinic, thiol, etc.) incorporated in graphene oxide has been studied towards the anodic corrosion resistance. Heteroatom functionalized carbon supports possess modified electronic properties, surface oxygen content, and hydrophilicity, which are crucial in governing electrochemical corrosion in the alkaline oxidative environment. Evidently, electron-withdrawing groups in NGO support (pyridinic, cyano, nitro, etc) and its lower oxygen content impart maximum corrosion resistance and anodic stability in comparison to the other sulfur-doped and co-doped graphene oxide support. In this report, we establish the baseline evaluation of carbon-supported OER electrocatalysts by a systematic analysis of activity and substrate corrosion resistance. The result of this study establishes the role of surface composition of the doped supports while for designing a stable, corrosion-resistant OER electrocatalyst. 相似文献
16.
17.
《Ceramics International》2022,48(12):16877-16884
Oxygen selective membrane on the base of cermet δ-Bi2O3/Ag with an interpenetrating structure has the maximum potential efficiency of air separation. However, the degradation processes, including the phase degradation of fluorite δ-Bi2O3, do not make it possible to create a membrane with the required perfection and durability. In this work, the ordering of oxygen vacancies with the transformation of fluorite into the rhombohedral phase (S.G. R-3) was studied by powder HT XRD in situ at 600 °C on dense Bi0.78Er0.2Hf0.02O1.51 ceramics. Fast regeneration of disordered fluorite occurs at T = 640–700 °C. The phase degradation of fluorite due to the segregation of dopants at the second stage leads into stable phases - sillenite, tetragonal or rhombohedral phase (S.G. R-3m), depending on the composition of δ-Bi2O3. Fast regeneration of fluorite occurs when heated to 820 °C, which is unacceptable for membranes. Analysis of all available data allows us to propose approaches to optimize the composition of δ-Bi2O3 and technical solutions for creating durable oxygen selective membranes with promising use in distributed multigeneration. As a result of the analysis, a new solid electrolyte with better parameters was obtained. 相似文献
18.
19.
Zeyu Zhao Jun Gao Yuqing Meng Kyle S. Brinkman Jianhua Tong 《Ceramics International》2021,47(8):11313-11319
The state-of-the-art protonic ceramic conductor BaZr0.8Y0.2O3-δ (BZY20) requires an extremely high sintering temperature (≥1700 °C) to achieve the desired relative density and microstructure necessary to function as a proton conducting electrolyte. In this work, we developed a cold sintering pretreatment assisted moderate-temperature sintering method for the fabrication of high-quality pure BZY20 pellets. BZY20 pellets with high relative density of ~94% were fabricated with a final sintering temperature of 1500 °C (200 °C lower than the traditional sintering temperature). A comparison with BZY20 control samples indicated that the proper amount of BaCO3 introduced on the BZY20 particle surface and the high green density achieved by cold sintering pretreatment were the main drivers for lowering the sintering temperature. The electrical conductivity measurement by electrochemical impedance spectroscopy showed that the as-prepared BZY20 pellets have a proton conductivity comparable to the state-of-the-art values. The cold sintering pretreatment outlined in this work has the potential to lower the sintering temperatures for similar types of protonic ceramic materials under consideration for a wide range of energy conversion and storage applications. 相似文献
20.
Cho-Yi Chen Masaoki Kawasumi Tien-Yun Lan Chi-Lam Poon Yi-Sian Lin Pin-Jou Wu Yao-Chung Chen Bing-Hong Chen Cheng-Hsien Wu Jeng-Fan Lo Rueyhung Roc Weng Yi-Chen Sun Kai-Feng Hung 《International journal of molecular sciences》2021,22(1)
Endoplasmic reticulum (ER) stress response is an adaptive program to cope with cellular stress that disturbs the function and homeostasis of ER, which commonly occurs during cancer progression to late stage. Late-stage cancers, mostly requiring chemotherapy, often develop treatment resistance. Chemoresistance has been linked to ER stress response; however, most of the evidence has come from studies that correlate the expression of stress markers with poor prognosis or demonstrate proapoptosis by the knockdown of stress-responsive genes. Since ER stress in cancers usually persists and is essentially not induced by genetic manipulations, we used low doses of ER stress inducers at levels that allowed cell adaptation to occur in order to investigate the effect of stress response on chemoresistance. We found that prolonged tolerable ER stress promotes mesenchymal–epithelial transition, slows cell-cycle progression, and delays the S-phase exit. Consequently, cisplatin-induced apoptosis was significantly decreased in stress-adapted cells, implying their acquisition of cisplatin resistance. Molecularly, we found that proliferating cell nuclear antigen (PCNA) ubiquitination and the expression of polymerase η, the main polymerase responsible for translesion synthesis across cisplatin-DNA damage, were up-regulated in ER stress-adaptive cells, and their enhanced cisplatin resistance was abrogated by the knockout of polymerase η. We also found that a fraction of p53 in stress-adapted cells was translocated to the nucleus, and that these cells exhibited a significant decline in the level of cisplatin-DNA damage. Consistently, we showed that the nuclear p53 coincided with strong positivity of glucose-related protein 78 (GRP78) on immunostaining of clinical biopsies, and the cisplatin-based chemotherapy was less effective for patients with high levels of ER stress. Taken together, this study uncovers that adaptation to ER stress enhances DNA repair and damage tolerance, with which stressed cells gain resistance to chemotherapeutics. 相似文献